Fischer-type gold(I) carbene complexes stabilized by aurophilic interactions.

نویسندگان

  • Daniela I Bezuidenhout
  • Belinda van der Westhuizen
  • Amos J Rosenthal
  • Michael Wörle
  • David C Liles
  • Israel Fernández
چکیده

The synthesis and structure of rare acyclic alkoxy- and aminocarbene complexes of gold(i) are reported, including a novel ferrocenophane dinuclear biscarbene complex. X-Ray diffraction analyses and DFT calculations reveal that these complexes are stabilized by genuine aurophilic interactions.

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عنوان ژورنال:
  • Dalton transactions

دوره 43 2  شماره 

صفحات  -

تاریخ انتشار 2014